(E)-3-(3,5-Dimeth­oxy­phen­yl)-1-(2-meth­oxy­phen­yl)prop-2-en-1-one

نویسندگان

  • Yoongho Lim
  • Dongsoo Koh
چکیده

In the title mol-ecule, C18H18O4, the dihedral angle between the benzene rings is 52.52 (7)°. The C=C bond of the central enone group adopts a trans conformation. The relative conformation of the two double bonds in the enone group is s-transoid. In the crystal, mol-ecules are linked by pairs of weak C-H⋯O hydrogen bonds, forming inversion dimers.

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منابع مشابه

(E)-1-(3,5-Difluoro­phen­yl)-3-(2,4-dimeth­oxy­phen­yl)prop-2-en-1-one

The title compound, C(17)H(14)F(2)O(3), is approximately planar, the dihedral angle between the rings being 5.46 (2)°. The H atoms of the central propenone group are trans. The crystal structure is stabilized by inter-molecular C-H⋯F hydrogen bonds.

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(E)-3-(3,5-Dimeth­oxy­phen­yl)-1-(1-hy­droxy­naphthalen-2-yl)prop-2-en-1-one

In the title mol-ecule, C21H18O4, the C=C bond of the central enone group adopts a trans conformation. The dihedral angle formed by the naphthalene ring system and the benzene ring is 2.97 (11)°. The hy-droxy group is involved in an intra-molecular O-H⋯O hydrogen bond. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into chains along [001].

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(E)-1-(2-Hy­droxy-4,6-dimeth­oxy­phen­yl)-3-(4-meth­oxy­phen­yl)prop-2-en-1-one from Kaempferia rotunda Val.

The planar -CH=CHC(=O)- fragment (r.m.s. deviation = 0.074 Å) in the title compound, C(18)H(18)O(5), connects the planar hy-droxy-dimeth-oxy-phenyl (r.m.s. deviation = 0.039 Å) and meth-oxy-lphenyl (r.m.s. deviation = 0.021 Å) parts. The central fragment forms a dihedral angle of 13.7 (1)° with the hy-droxy-dimeth-oxy-phenyl part and 32.0 (1)° with the meth-oxy-phenyl part. The hy-droxy group f...

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(E)-1-(3,5-Di­meth­oxy­phen­yl)-3-(3-meth­oxy­phen­yl)prop-2-en-1-one

In the title mol-ecule, C18H18O4, the C=C bond of the central enone group adopts a trans conformation. The relative conformation of the C=O and C=C bonds is s-cisoid. The dihedral angle between the planes of the benzene rings is 29.49 (12)°. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].

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(E)-1-(3-Bromo­phen­yl)-3-(3,4-dimeth­oxy­phen­yl)prop-2-en-1-one

The mol-ecular structure of the title compound, C(17)H(15)BrO(3), consists of a bromo-phenyl and a 3,4-dimeth-oxy-phenyl group linked through a prop-2-en-1-one spacer. The C=C double bond displays an E conformation, while the carbonyl group shows an S-cis conformation relative to the double bond.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013